A Review on Acid Gas Injection into Geological Formations with the Aim of Enhanced Oil Recovery and Environmental Protection: Theoretical Foundations

Document Type : Research Paper

Authors

Petroleum Engineering Department, Ahwaz Faculty of Petroleum, Petroleum University of Technology, Iran

Abstract

Nowadays, sulfur recovery processes tend to be no longer economic, as well as having various operational problems. They also discharge large amounts of CO2 into the atmosphere. The alternative is to compress and inject acid gas into geological formations with the purpose of enhanced oil recovery and acid gas sequestration for environmental protection. In this review article, after providing the initial definitions in acid gas studies, sour gas sweetening methods and their most prominent operational difficulties have been introduced and compared with each other by us. By completing the sour gas sweetening process, a problematic flow of acid gas is produced. Next, we address the theoretical foundations, the application scope, cost, and operational-economic challenges of different sulfur recovery methods in a try to explain the importance of exhausting the issue of acid gas injection in geological formations from a technical and economic point of view. We also present and discuss the principles of acid gas injection into geological formations, the criteria for selecting a suitable formation for injection, and the trapping mechanisms of acid gas.
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Keywords


[1] Maddox RN, Sheerar LF (1982) Gas conditioning and processing, volume 4: Gas and liquid sweetening (Campbell JM Ed. 3 ed.), Campbell Petroleum Series. ##
[2] Carroll JJ (2010) Acid gas injection and carbon dioxide sequestration, John Wiley and Sons. ##
[3] Sour gas handling compliance (2020) https://www.tceq.texas.gov/assistance/industry/oil-and-gas/sour-gas-handling-compliance. ##
[4] Huo D (2012) The global sour gas problem, Stanford Energy Journal, 2. ##
[5] Falcao LdSM (2016) Simulation study of acid gas injection into the cherry canyon formation, delaware basin, new mexico, MSc thesis, New Mexico Institute of Mining and Technology, United States of America.  ##   
[6] H2S (hydrogen sulfide) – knowledge can save lives (2013) Dräger. ##
[7] H2S – a growing challenge in the oil & gas industry (2013), Dräger. ##
[8] Hill FB, Woodwell G, Pecan E (1973) Atmospheric sulfur and its links to the biota, Brookhaven National Laboratory, Upton, 24, (USA). ## [9] Mokhatab S, Poe WA,Mak JY (2019) Chapter 7 - natural gas treating Handbook of natural gas transmission and processing (fourth edition), 231-269, Gulf Professional Publishing. ##
[10] Seto C, Beliveau D (2000) Reservoir souring in the caroline field, SPE/CERI Gas Technology Symposium, Canada. ##
[11] Badrak RP (2018) Nace mr0175/iso 15156: Update on current document and where are we going, Corrosion 2018 Conference, United States of America. ##
[12] Canada SCo (2011) CSA Z662 oil and gas pipeline systems. ##
[13] Institute A P, Department APIP (1978) Api recommended practices for safe drilling of wells containing hydrogen sulfide, American Petroleum Institute. ##
[14] Institute A P (1995) API Recommended Practices Conducting Oil and Gas Processing and Gas Processing Plant Operations Involving Hydrogen Sulfide, American Petroleum Institute. ##
[15] Chou C, Organization WH (2003) Hydrogen sulfide: Human health aspects, World Health Organization. ##
[16] Orr W L (1974) Changes in sulfur content and isotopic ratios of sulfur during petroleum maturation—study of big horn basin paleozoic oils, AAPG bulletin, 58, 11: 2295-2318. ##
[17] Hyne J, Derdall G (1980) Sulfur deposition in reservoirs and production equipment: Sources and solutions, Annual Gas Conditioning Conference, University of Oklahoma, Norman, Oklahoma, March. ##
[18] Rosnes J, Graue A, Torleiv L (1991) Activity of sulfate-reducing bacteria under simulated reservoir conditions, SPE Production Engineering, 6, 02: 217-220. ##
[19] Marcano N, Larter S, Snowdon L,Bennett B (2013) An overview of the origin, pathways and controls of H2S production during thermal recovery operations of heavy and extra-heavy oil, Integration, GeoConvention. ##
[20] Li Q, Li X, Du L, Liu G, Liu X, Wei N (2012) Potential sites and early opportunities of acid gas re‐injection in china, Sour gas and related technologies: 129-142. ##
[21] Engineering data book (2004) (12 ed.), Gas Processors Suppliers Association. ##
[22] Foral A J, Al-Ubaidi B H, Floyd F M, Leppin D (1995) Evaluation of H2S scavenger technologies: Topical report, task, 55, M.W. Kellogg Company. ##
[23] Kidnay A J, Parrish W R, McCartney D G (2019) Fundamentals of natural gas processing, CRC press. ##
[24] Manning F S,Thompson R E (1991) Oilfield processing of petroleum, 1, Natural gas, Penwell Publishing Company.
[25] Branan CR (2005) 13 - gas treating: Chapter updated by Chris Higman. In Branan CR (Ed.), Rules of thumb for chemical engineers (fourth edition), 213-220, Burlington, Gulf Professional Publishing. ##
[26] Kurimura H, Rochelle G, Sepehrnoori K (1993) An expert system to select acid gas treating processes for natural gas processing plants, Gas Separation & Purification, 7, 3: 151-158. ##
[27] Bergel M, Tierno I (2009) Sweetening technologies: a look at the whole picture. ##
[28] Kohl A L, Nielsen R B (1997) Gas purification, Gulf Professional Publishing. ##
[29] Bahadori A (2014) Natural gas processing, Gulf Professional Publishing. ##
[30] Mokhatab S, Poe WA,Mak JY (2019) Chapter 8 - sulfur recovery and handling Handbook of natural gas transmission and processing (fourth edition), 271-305, Gulf Professional Publishing. ##
[31] Eow J S (2002) Recovery of sulfur from sour acid gas: A review of the technology, Environmental Progress, 21, 3: 143-162. ##
[32] Nehb W,Vydra K (2000) Sulfur, Ullmann's Encyclopedia of Industrial Chemistry. ##
[33] Sulfur Process Technology, Linde Process Plants, Inc. ##
[34] اسفندیاری ک، شاهسوند ا، " ارائه راهکارهای مناسب جهت رفع تنگناهای عملیاتی موجود در واحدهای بازیافت گوگرد درپالایشگاه های گاز داخل کشور "، چهاردهمین کنگره ملی مهندسی شیمی ایران، دانشگاه صنعتی شریف، تهران، ایران، 1391. ##
[35] محمدی م، محمدی م ح، "روش‌هایی برای بالا بردن راندمان فرآیند بازیافت گوگرد کلاوس با توجه به روندقدیمی آن و مروری بر فرآیندهای نوین جایگزین آن"، اولین همایش ملی فناوری‌های نوین در صنایع نفت و گاز، دانشگاه آزاد اسلامی واحد امیدیه، امیدیه، ایران، 1389. ##
[36] Clark P D (2006) Sulfur and hydrogen sulfide recovery, Kirk‐Othmer encyclopedia of chemical technology. ##
[37] Schreiner B (2012) Oxygen enriched vs. Air-only operation at Claus units field tests are teaching lessons - especially in view of ammonia destruction, Sulfur International Conference And Exhibition, Germany. ##
[38] Heisel M P, Schreiner B, Zambrano MdL C (2007) Oxygen enrichment in Claus plants in view of the production of Clean Fuels, Hydrocarbon Processing. ##
[39] Gowdy H W, Bertram R V (1998) UOP’s Selectox process improvements in the technology, the 48th Annual Laurance Reid Gas Conditioning Conference, Norman, OK, USA. ##
[40] Jones S G, Bertram R V (2001) Lisbon plant Selectox unit 7 years operating performance, the 51th Annual Laurance Reid Gas Conditioning Conference, Norman, OK, USA. ##
[41] Nagl G, Rouleau W, Watson J (2003) Consider optimized iron-redox processes to remove sulfur, Hydrocarbon Processing.
[42] Smit C, Heyman E (1999) Present status Sulferox process, Process GRI Sulfur Recovery Conference, San Antonio, Texas. ##
[43] Dalrymple D, Srinivas G (1999) Crystasulf liquid redox and TDA gas phase H2S conversion technologies for sour gas treating, GPA 78th Annual Convention, Nashville, United States of America. ##
[44] McIntush K, Beitler C, Swadener M, Wallace C (2010) Screening processes for removal of H2S from enhanced oil recovery CO2 streams, Proceedings of the 60th Laurance Reid Gas Conditioning Conference. ##
[45] Dalrymple D A, Trofe T W, Evans J M (1989) Liquid redox sulfur recovery options, costs, and environmental considerations, Environmental Progress, 8, 4, 217-222. ##
[46] Cline C, Hoksberg A, Abry R, Janssen A (2003) Biological process for H2S removal from gas streams: The Shell-Paques/Thiopaq™ gas desulfurization process, Proceedings of the Laurance Reid gas conditioning conference. ##
[47] Kijlstra SW, Janssen A,Arena B (2001) Biological process for H2S removal from (high pressure) gas: The Shell-Paques/Thiopaq gas desulfurization process, Proceedings of the Laurance Reid Gas Conditioning Conference. ##
[48] Osborne W J, Earl C B (1975) Recent experience of the Wellman-Lord sulfur dioxide recovery process, ACS Publications.
[49] مهدی‌پور ح، دهقانی اشکذری ا، حیاتی ر، "مقایسه فنی و اقتصادی روش‌های خنک‌سازی گاز داغ خروجی از راکتور واحد پاکسازی گاز پسماند"، نشریه مهندسی گاز ایران، شماره 4، صفحات 76-70، 1395. ##
[50] Garside M (2020) Global sulfur production by country 2019, https://www.statista.com/statistics/1031181/sulfur-production-globally-by-country/.##
[51] Li Q, Liu X, Du L, Bai B, Fang Z, Jing M, Li X (2013) Economics of acid gas injection with comparison to Sulfur Recovery in China, Energy Procedia, 37: 2505-2510. ##
[52] Bachu S, Gunter WD (2005) Overview of acid-gas injection operations in western Canada, In Rubin ES, Keith DW, Gilboy CF, Wilson M, Morris T, Gale J, Thambimuthu K (Eds.), Greenhouse Gas Control Technologies 7, 443-448, Oxford, Elsevier Science Ltd. ##
[53] Bahrami A, Jamialahmadi M, Moghadasi J, Alimohammadi N (2013) Simulation study of co2 sequestration potential of the Mary Lee coal zone, black warrior basin, Environmental Earth Sciences, 70, 6: 2501-2509. ##
[54] Bennion D B, Thomas E, Bennion D W, Bietz R (1996) Formation screening to minimize permeability impairment associated with acid gas or sour gas injection/disposal, Annual Technical Meeting. ##
[55] Bennion D, Thomas F, Schulmeister B, Imer D, Shtepani E, Becker L (2002) The phase behavior of acid disposal gases and the potential adverse impact on injection or disposal operations, Canadian International Petroleum Conference. ##
[56] Wang S, Carroll J J (2006) Model calculates acid gas injection profiles, Oil & gas journal, 104, 33: 61-69. ##
[57] Carroll J (2002) Phase equilibria relevant to acid gas injection, part 1-non-aqueous phase behaviour, Journal of Canadian Petroleum Technology, 41, 06. ##
[58] Carroll J (2002) Phase equilibria relevant to acid gas injection: Part 2-aqueous phase behaviour, Journal of Canadian Petroleum Technology, 41, 07. ##
[59] معتقد ا، کمری م، رضائیان ا، طباطبایی نژاد س.ع، "بررسی انواع سیستم‌های زمین‌شناسی و مکانیزم‌های ذخیره‌سازی در جداسازی دی اکسید کربن"، سومین کنفرانس علمی مهندسی مخازن هیدروکربوری و صنایع##
[60] Ajayi T, Gomes J S, Bera A (2019) A review of co2 storage in geological formations emphasizing modeling, monitoring and capacity estimation approaches, Petroleum Science, 16, 5: 1028-1063. ##
[61] Shukla Potdar R,Vishal V (2016) Trapping mechanism of CO2 storage in deep saline aquifers: Brief review Geologic carbon sequestration: Understanding reservoir behavior, Cham, Springer International Publishing, 47-58. ##
[62] Zhang D, Song J (2014) Mechanisms for geological carbon sequestration, Procedia IUTAm, 10, 0: 319-327. ##
[63] Pentland C H, El-Maghraby R, Georgiadis A, Iglauer S, Blunt M J (2011) Immiscible displacements and capillary trapping in CO2 storage, Energy Procedia, 4: 4969-4976. ##
[64] Shi J Q, Xue Z, Durucan S (2011) Supercritical CO2 core flooding and imbibition in Berea sandstone — CT imaging and numerical simulation, Energy Procedia, 4: 5001-5008. ##
[65] Doughty C, Pruess K, Benson S M, Hovorka S D, Knox P R, Green C T (2001) Capacity investigation of brine-bearing sands of the Frio formation for geologic sequestration of CO2, GCCC Texts and Reports. ##
[66] DePaolo D J, Cole D R (2013) Geochemistry of geologic carbon sequestration: An overview, De Gruyter. ##
[67] Espinoza D N, Kim S H, Santamarina J C (2011) CO2 geological storage — geotechnical implications, KSCE Journal of Civil Engineering, 15, 4: 707-719. ##
[68] Marieni C, Přikryl J, Aradóttir ES, Gunnarsson I, Stefánsson A (2018) Towards ‘green’ geothermal energy: Co-mineralization of carbon and sulfur in geothermal reservoirs, International Journal of Greenhouse Gas Control, 77: 96-105. ##