مطالعه آزمایشگاهی تاثیر نوع سورفکتانت در حضور نفت‌های مختلف بر پایداری فوم

نوع مقاله : مقاله پژوهشی

نویسندگان

1 گروه مهندسی نفت، پردیس بین المللی کیش، دانشگاه تهران، کیش، ایران

2 انستیتو مهندسی نفت، دانشکده مهندسی شیمی، دانشکدگان فنی، دانشگاه تهران، ایران

10.22078/pr.2025.5673.3517

چکیده

در سال‌های اخیر افزایش تفاضای نفت باعث شده تا نیاز شدیدی به بهبود فن‌آوری‌های ازدیاد برداشت احساس شود. یکی از روش‌های متداول برای ازدیاد برداشت نفت، روش تزریق گاز است. در هنگام تزریق گاز به مخزن مشکلاتی نظیر بالاروی ثقلی به‌علت چگالی کم گاز نسبت به نفت باعث کاهش بازدهی این روش می‌شود. فوم می‌تواند با کاهش تراویی گاز، سبب بهبود تحرک‌پذیری و افزایش ازدیاد‌ برداشت شود. فوم از مخلوط گاز و مایع ماده فعال سطحی تشکیل شده است. اما فوم پایدار شده به‌وسیله ماده فعال سطحی تحت تاثیر عوامل مختلفی از جمله دما، فشار، نوع سنگ مخزن، شوری و ترکیبات نفت می‌باشد. هدف این مطالعه بررسی مقاومت دو سورفکتانت آنیونی SDS و کاتیونی CTAB در حضور اجزای قطبی نفت می‌باشد. نتایج نشان می‌دهد که سورفکتانت آنیونی SDS از سورفکتانت کاتیونی CTAB در غیاب ترکیبات نفت، پایدارتر می‌باشد. همچنین با افزایش غلظت شش نوع نفت مختلف از 1 به 4% حجمی، پایداری حاصل از سورفکتانت آنیونی حدود 5/21% کاهش یافته است، درصورتی‌که پایداری فوم حاصل از سورفکتانت کاتیونی حدود 8/38% کاهش می‌یابد، که این نشان‌دهنده مقاومت بیشتر سورفکتانت آنیونی در حضور ترکیبات مختلف نفت می‌باشد.

کلیدواژه‌ها

موضوعات

عنوان مقاله [English]

Experimental Study on the Effect of Surfactant Type in the Presence of Different Oils on Foam Stability

نویسندگان [English]

  • Davood Dianati 1
  • Siavash Riahi 2
1 Department of Petroleum Engineering, Kish International Campus, University of Tehran, Kish Island, Iran
2 Institute of Petroleum Engineering, School of Chemical Engineering, College of Engineering, University of Tehran, Tehran, Iran
چکیده [English]

In recent years, the increasing demand for oil has highlighted an urgent need to enhance Enhanced Oil Recovery (EOR) technologies. One common method for EOR is gas injection. However, during gas injection into reservoirs, issues such as gravity drainage occur because the lower density of gas compared to oil reduces the efficiency of this process. Furthermore, foam can improve gas mobility control and enhance oil recovery by reducing the mobility of gas. In addition, foam consists of a gas phase dispersed within an aqueous surfactant solution; however, the stability of surfactant-stabilized foam is influenced by various factors, including temperature, pressure, reservoir rock type, salinity, and oil composition. Moreover, the objective of this study was to investigate the stability of two surfactants—the anionic SDS and the cationic CTAB—in the presence of polar oil components. Also, the results indicate that the anionic surfactant SDS is more stable than the cationic surfactant CTAB in the absence of oil compounds. Furthermore, as the concentration of six different types of crude oil was increased from 1 vol% to 4 vol%, the foam stability generated by the anionic surfactant decreased by approximately 21.5%, whereas the foam stability generated by the cationic surfactant decreased by about 38.8%. This demonstrates the greater resistance of the anionic surfactant in the presence of various oil components.

کلیدواژه‌ها [English]

  • Enhanced Oil Recovery
  • Foam Stability
  • Anionic Surfactant SDS
  • Cationic Surfactant CTAB
  • Oil Components

مراجع

[1]. Li, S., Li, Z., & Wang, P. (2016). Experimental study of the stabilization of CO2 foam by sodium dodecyl sulfate and hydrophobic nanoparticles. Industrial & Engineering Chemistry Research, 55(5), 1243-1253.‏https://doi/.org/10.1021/acs.iecr.5b04443.##
[2]. Nguyen, P., H. Fadaei, and D. Sinton. (2014). Pore-scale assessment of nanoparticle-stabilized CO2 foam for enhanced oil recovery. Energy & Fuels, 28(10), 6221-6227. https://doi.org/10.1021/ef5011995. ##
[3]. Rafati, R., H. Hamidi, and A. K. Idris. (2012). Application of sustainable foaming agents to control the mobility of carbon dioxide in enhanced oil recovery. Egyptian Journal of Petroleum, 21(2), 155-163. https://doi.org/10.2118/163287-MS. ##
[4]. Sun, Q., Z. Li, S. Li, et al. (2014). Utilization of surfactant-stabilized foam for enhanced oil recovery by adding nanoparticles. Energy & Fuels, 28(4), 2384-2394. https://doi.org/10.1021/ef402453b. ##
[5]. Hussain, A., et al. (2017). Effect of oil on gravity segregation in SAG foam flooding. In IOR 2017-19th European Symposium on Improved Oil Recovery.https://doi.org/10.3997/2214-4609.201700342. ##
[6]. Rossen, W. R. (1996). Foams in enhanced oil recovery. In Foams: Theory, Measurements and Applications, 57, 413-464. ##
[7]. Valenzuela, G., et al. (2013). Foam sclerosants are more stable at lower temperatures. European Journal of Vascular and Endovascular Surgery, 46(5), 593-599. https://doi.org/10.1016/j.ejvs.2013.08.012. ##
[8]. Rosen, M. J., & J. T. Kunjappu. (2012). Surfactants and interfacial phenomena. John Wiley & Sons.https://doi.org/10.1002/9781118228920##
[9]. Bello, A., A. Ivanova, D. Bakulin, et al. (2024). An experimental study of foam-oil interactions for nonionic-based binary surfactant systems under high salinity conditions. Scientific Reports, 14(1), 12208.https://doi.org/10.1038/s41598-024-62610-1. ##
[10]. Lu, T., Z. Li, & L. Du. (2024). Enhancing foam stability and addressing asphaltene deposition for improved oil recovery in CCUS applications using aerogel nanoparticles. Chemical Engineering Journal, 481, 148290.https://doi.org/10.1016/j.cej.2023.148290. [11]. Youssif, M. I., A. E. Shoukry, K. V. Sharma, L. Goual, & M. Piri. (2024). The effects of brine salinity and surfactant concentration on foam performance in fractured media. Energy & Fuels, 38(20), 19494-19508.https://doi.org/10.1021/acs.energyfuels.4c02706. ##
[12]. Lee, J., A. Nikolov, & D. Wasan. (2012). Stability of aqueous foams in the presence of oil: On the importance of dispersed vs solubilized oil. Industrial & Engineering Chemistry Research, 52(1), 66-72.https://doi.org/10.1021/ie301102m. ##
[13]. Simjoo, M., T. Rezaei, A. Andrianov, & P. L. J. Zitha. (2013). Foam stability in the presence of oil: Effect of surfactant concentration and oil type. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 438, 148-158. https://doi.org/10.1016/j.colsurfa.2013.05.062. ##
[14]. Lee, J., A. Nikolov, & D. Wasan. (2014). Surfactant micelles containing solubilized oil decrease foam film thickness stability. Journal of Colloid and Interface Science, 415, 18-25. https://doi.org/10.1016/j.jcis.2013.10.014. ##
[15]. Piroird, K., E. Lorenceau, & A. L. Biance. (2014). Oil repartition in a foam film architecture. Soft Matter, 10(36), 7061-7067.https:// doi.org/10.1039/C4SM00538D. ##
[16]. Sonoda, J., T. Sakai, & Y. Inomata. (2014). Liquid oil that flows in spaces of aqueous foam without defoaming. The Journal of Physical Chemistry B, 118(18), 5114-5119. https://doi.org/10.1021/jp501599v. ##
[17]. Sun, L., W. Pu, J. Xin, P. Wei, B. Wang, Y. Li, & C. Yuan. (2015). High temperature and oil tolerance of surfactant foam/polymer–surfactant foam. RSC Advances, 5(30), 23410-23418. https://doi.org/10.1039/C4RA17216J. ##
[18]. Osei-Bonsu, K., N. Shokri, & P. Grassia. (2015). Foam stability in the presence and absence of hydrocarbons: From bubble-to bulk-scale. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 481, 514-526. https://doi.org/10.1016/j.colsurfa.2015.06.023. ##
[19]. Tang, J., S. V. Bonnieu, & W. R. Rossen. (2017). The effect of oil on steady-state foam flow regimes in porous media. In IOR 2017-19th European Symposium on Improved Oil Recovery. https://doi.org/10.3997/2214-4609.201700345. ##
[20]. Varade, S. R., & P. Ghosh. (2017). Foaming in aqueous solutions of zwitterionic surfactant: Effects of oil and salts. Journal of Dispersion Science and Technology, 38, 1-15. https://doi.org/10.1080/01932691.2017.1283509. ##
[21]. Beheshti, E., S. Riahi, & M. Riazi. (2022). Impacts of oil components on the stability of aqueous bulk CO2 foams: An experimental study. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 648, 129328. https://doi.org/10.1016/j.colsurfa.2022.129328. ##
[22]. Wang, Z., Y. Xu, N. Khan, C. Zhu, & Y. Gao. (2023). Effects of the surfactant, polymer, and crude oil properties on the formation and stabilization of oil-based foam liquid films: Insights from the microscale. Journal of Molecular Liquids, 373, 121194. https:// doi.org/10.1016/j.molliq.2022.121194##
[23]. Balakirisnan, A., Jaafar, M. Z., Sidek, M. A., Yakasai, F., Nwaichi, P. I., Ridzuan, N., ... & Agi, A. (2024, August). Effect of Oil Polarity on Surfactant Foam Properties at Bulk and Macroscopic Scale. In SPE Nigeria Annual International Conference and Exhibition (p. D021S012R005). SPE.https://doi.org/10.2118/221592-MS‏##
[24]. Babamahmoudi, S., & S. Riahi. (2018). Application of nanoparticle for enhancement of foam stability in the presence of crude oil: Experimental investigation. Journal of Molecular Liquids, 264, 499-509. https://doi.org/10.1016/J.MOLLIQ.2018.04.093. ##
[25]. Naskar, B. (2025). Micellization and physicochemical properties of CTAB in aqueous solution: Interfacial properties, energetics, and aggregation number at 290 to 323 K. Colloids and Interfaces, 9(1), 4. https://doi.org/10.3390/colloids9010004.
[26]. Parvaneh, R., S. Riahi, & M. N. Lotfollahi. (2022). Experimental evaluation of a polymer foam agent on foam stability: ## Concern to surfactant, nanoparticle, and salinity. SPE Journal, 27(3), 1462–1479. https://doi.org/10.2118/209209-PA. ##
[27]. Majeed, T., T. I. Sølling, & M. S. Kamal. (2020). Foam stability: The interplay between salt, surfactant, and critical micelle concentration. Journal of Petroleum Science and Engineering, 187, 106871. https://doi.org/10.1016/j.petrol.2019.106871. ##
[28].Massarweh, O., & A. S. Abushaikha. (2020). The use of surfactants in enhanced oil recovery: A review of recent advances. Energy Reports, 6, 3150–3178. https://doi.org/10.1016/j.egyr.2020.11.009. ##
[29]. Parvaneh, R., R. Kianpour & S. Riahi. (2025). Experimental Investigation of New Eco-Friendly Nanosized Particles as Foam Stabilizers Under High Salinity Conditions. https://doi.org/10.1016/j.surfin.2025.107913. ##
[30]. Palizdan, S., et al. (2020). Experimental study of in-situ W/O emulsification during the injection of MgSO4 and Na2CO3 solutions in a glass micromodel. Oil & Gas Science and Technology, 75, 54.https://doi.org/10.2516/ogst/2020072. ##
[31]. Rafati, R., et al. (2018). Experimental investigation of emulsified oil dispersion on bulk foam stability. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 554, 110–121. https://doi.org/10.1016/j. colsurfa.2018.06.043. ##
[32]. Fainerman, V. B., R. Miller, E. V. Aksenenko, & A. V. Makievski. (2001). Equilibrium adsorption properties of single and mixed surfactant solutions. In Studies in Interface Science (Vol. 13, pp. 189-285). Elsevier.https://doi.org/10.1016/S1383-7303(01)80064-8##
[33]. Schramm, L. L., & J. J. Novosad. (1990). Micro-visualization of foam interactions with a crude oil. Colloids and Surfaces, 46(1), 21-43. https://doi.org/10.1016/0166-6622(90)80046-7. ##
[34]. Bergeron, V. (1993). Forces and Structure in Surfactant-Laden Thin-Films. Ph. D. Thesis. (Note: DOIs are typically not assigned to PhD theses unless published by a specific publi##
پژوهش نفت
دوره 35، 1404-6 - شماره پیاپی 145
بهمن و اسفند 1404
صفحه 135-148

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